yea it can be tricky for all of us to get email thru enterprise firewalls. Generally if you're sending a lot of email thru your advocacy platform, it's worth the effort to set up the email infrastructure so that you can send via whatever platform you use but the emails still come from your corporate email domain (that should already be whitelisted by your customers so it doesn't get flagged/blocked)
have you set up custom subdomains w/DNS records and SPF + DKIM + DMARC and all that?